Methyl iodide
  (iodomethane)
 
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MolecularFormula CH3I
  CAS No. 74-88-4
 
Molecular Weight 141.95
 
Typical Properties
Appearance Colorless transparent liquid, with sweet ether-like odor
Specific gravity d204 2.28
Melting point -66.45°C
Boiling point 42.5°C
Refractive index n21D 1.5293
Solubility in water 1.4g/100 g (20°C)
Readily soluble in alcohol, ether, and carbon tetrachloride.
Reactivity Releases iodide in light and turns brown
Decomposition temperature: 270°C
 
Specifications
Item ISE Standard JIS K8919-1981 Special Class
Fraction (41.5 ~ 43°C) 95v/v% min. 95v/v min.
Water content 0.1% max. 0.1% max.
Non-volatile constituents 0.1% max. 0.1% max.
Acidity To pass test To pass test
Assay 98.0% min. 98.0% min.
 
Packing
30 l Stainless steel drum
Net weight: 40kg. Mixed with copper foil
 
Applications
Medicines, organic chemicals synthesis (methylation agent), microcopy (utilization of refractive index), soil disinfectant.
 
Hazards
1) Fire and explosion: Noncombustible, non-inflammable, and on-explosive
2) Gas generation: Methyl iodide fumes
 
Toxicity
LD50 oral-rat: 200 mg/kg or 50 mg/kg
TLV: 10 ppm air
Toxic, and cutaneously absorbed. When fumes are inhaled, the lung liver, kidney, and central nervous system are damaged, resulting in dizziness, sleepiness, nausea, diarrhea, speech disorder, ataxia, muscle convulsion, etc.
Acute poisoning is caused at 100 ~ 500 ppm in air, and death at 6000 ~ 8600 ppm.
 
First aid
1) Rinse eyes immediately with running water for over 15 minutes.
2) Wash skin with running water and soap.
3) Remove contaminated clothing immediately, and wash contaminated skin areas thoroughly.
 
Handling & Storage
1) Tightly seal containers, and store in a well-ventilated, cool, dark place.
2) Keep working area well ventilated, and measure gas concentration at regular intervals. Wear polyurethane gloves and impermeable garments.
 
Spillage
Eliminate all ignition sources in the neighborhood, absorb the spilled liquid with paper towels or vermiculite, and place these on a steel, glass or plastic pan to let the liquid evaporate. Burn the paper towels or vermiculite and wash the ground surface with soapy water.

 

 

  
 

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2.3.3 Triiodo allylalcohol
1,4-Diiododurene
2.2.2 Trifluoro-1-iodo ethane
2,3,5 Triiodo sodium benzoate
3,5-Diiodosalicyclic acid
4,4’-Diiododiphenyl
Ammonium iodide
Cetyl iodide
Chloramine - T
Dibutyl-N-N- diethylcarbamoylphosphonate (DDCP)
Diacetoamido-triiodobenzoic acid
Diiododiphenyl
Ethyl iodide
Ethylene diamine dihydrooiodide
Ethyltriphenyl phosphonium iodide
HF-Pyridine (pyridine hydrofluoride)
Hydroiodic acid solution
Iodic acid
Iodic acid (aqueous solution)
Iodine monocholoride
Iodine monocholoride HCL solution
Iodine pentafluoride
Iodo acetic acid
Iodobenzene
Iodoxybenzene
Iodoform
IPBC
Iodine disinfectant
Iso-propyl iodide
Isoquinoline butyliodide
Lithium iodide
m-Iodotoluene
Methyl flouride
Methyl iodide
Methylene iodide
Methyltributyl phosphonium iodide
n-Butyl iodide
n-Hexyl iodide
n-Octyl iodide
n-Propyl iodide
o-Iodotoluene
o-Iodonitrobenzene
o-Iodobenzoic acid
p-Iodobenzoic acid
p-Iodotoluene
p-Tolydiiodo methyl sulfonium
Silver iodide
Sodium iodate
Sodium iodide

Tetramethyl oxosulfonium Iodide
Tetraethyl ammonium Iodide
Tetramethyl ammonium Iodide
Tetrabutyl ammonium Iodide
Thymol iodide
Titanium iodide
Tin iodide
Trichloromelanmine
Triiodobenzoic acid
Triiodo phenol